No, mill isnt the same as discard
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Cards from the Classic Collection will not be legal in the Standard format

The deck as he currently has it outlined is as such: Creature: Archfiend of Ifnir, Chasm Skulker, Cloudblazer, Cunning Survivor, Curator of Mysteries, Dimir Infiltrator, Eternal Dragon, Horror of the Broken Lands, Magister Sphinx, Mulldrifter, Nimble Obstructionist, Ominous Sphinx, Prognostic Sphinx, Psychosis Crawler, Riverwise Augur, Ruthless Sniper, Shriekmaw, Street Wraith, Striped Riverwinder, Sun Titan, Thassa, God of the Sea, Void Winnower Planeswalker: Aminatou, the Fateshifter Instant: Ancient Excavation, Brainstorm, Countervailing Winds, Expunge, Forsake the Worldly, Muddle the Mixture, Radiants Judgment Sorcery: Akromas Vengeance, Approach of the Second Sun, Decree of Justice, Decree of Pain, Dream Cache, Essence Fracture, In Garruks Wake, Migratory Route, Mystic Speculation, Ponder, Razakeths Rite, Wander in Death Artifact: Abandoned Sarcophagus, Azorius Keyrune, Commanders Sphere, Conch Horn, Crystal Ball, Darksteel Ingot, Fluctuator, Gilded Lotus, Manalith, Orzhov Keyrune, Senseis Divining Top, Sol Ring, Thought Vessel Enchantment: Archmage Ascension, Astral Slide, Cast Out, Drake Haven, Faith of the Devoted, Lay Claim, New Perspectives, Soothsaying, Spirit Cairn, Thought Reflection Land: 3 Island, 2 Plains, 3 Swamp, Arcane Sanctum, Ash Barrens, Barren Moor, Blasted Landscape, Command Tower, Desert of the Mindful, Drifting Meadow, Drowned Catacomb, Evolving Wilds, Fetid Pools, Glacial Fortress, Halimar Depths, Irrigated Farmland, Isolated Chapel, Lonely Sandbar, Polluted Mire, Prairie Stream, Reliquary Tower, Remote Isle, Secluded Steppe, Sunken Hollow, Temple of Deceit, Temple of Enlightenment, Temple of Silence, Temple of the False God, Terramorphic Expanse Never Empty Handed Right off the bat, 50 of the 99 cards in the main deck are odd converted mana cost, which means there is a very high chance that Yannett will be casting spells without help

People have talked about this card as a way to deal with Thassas Oracle in higher power tables, but it just doesnt feel like a good answer